一些优化:CAN和PLC地址的优化
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CapMachine.Wpf/PPCalculation/REFPROP/FLUIDS/D2.FLD
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CapMachine.Wpf/PPCalculation/REFPROP/FLUIDS/D2.FLD
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Deuterium !Short name
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7782-39-0 !CAS number
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Deuterium !Full name
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D2 !Chemical formula {D2}
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Deuterium !Synonym
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4.0282 !Molar mass [g/mol]
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18.724 !Triple point temperature [K]
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23.661 !Normal boiling point [K]
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38.34 !Critical temperature [K]
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1679.6 !Critical pressure [kPa]
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17.23 !Critical density [mol/L]
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-0.136 !Acentric factor
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0.0 !Dipole moment [Debye]; (exactly zero due to symmetry)
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NBP !Default reference state
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10.0 !Version number
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1957 !UN Number :UN:
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cryogen !Family :Family:
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???? !Heating value (upper) [kJ/mol] :Heat:
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1S/H2/h1H/i1+1D !Standard InChI String :InChi:
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UFHFLCQGNIYNRP-VVKOMZTBSA-N !Standard InChI Key :InChiKey:
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8d757b40 (hydrogen) !Alternative fluid for mixing rules :AltID:
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639b18a0 !Hash number from InChI Key :Hash:
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!The fluid files contain general information about the fluid in the first 15 to 20 lines, followed by sections for the
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! equations of state, transport equations, and auxiliary equations. Equations of state are listed first. The NIST recommended
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! equations begin with a hash mark (#). The secondary equations begin with the @ symbol. These symbols can be swapped to
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! select a secondary equation as primary and the primary as secondary. The equation of state section also contains auxiliary
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! equations for the ideal gas heat capacity or ideal gas Helmholtz energy. Below the equations of state (both primary and
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! secondary) are the transport equations, first viscosity and then thermal conductivity. These are then followed by the
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! secondary equations if available. The transport section also contains auxiliary equations required to calculate either the
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! dilute gas state or the critical enhancement. At the end of the file are additional but not necessary auxiliary equations,
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! including simple equations for the vapor pressure, saturated liquid and vapor densities, melting line (for some fluids), and
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! sublimation line (for even fewer fluids). This section also contains the equations for dielectric constant and surface
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! tension if available. The sections are divided by different symbols (these being _-+=^*~) to aid the eye in locating a
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! particular section. Secondary equations are indented 10 spaces to avoid confusion with the NIST recommended equations. The
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! end of the fluid file is marked with @END. Anything below that is ignored.
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! compiled by E.W. Lemmon, NIST Physical and Chemical Properties Division, Boulder, Colorado
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! 04-03-98 EWL, Original version.
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! 06-21-10 CKL, Add ancillary equations.
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! 12-06-12 EWL, Add surface tension coefficients of Mulero et al. (2012).
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! 02-14-13 IAR, Add ancillary equations.
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! 02-14-13 IAR, Add new equation of state of Richardson.
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! 02-28-13 MLH, Add scaled hydrogen viscosity and thermal conductivity as estimates for deuterium.
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! 05-15-17 EWL, Change the hard coded VS0 model to the VS7 reverse Polish notation.
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________________________________________________________________________________
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#EOS !---Equation of state---
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FEQ !Helmholtz equation of state for deuterium of Richardson et al. (2014).
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:TRUECRITICALPOINT: 38.34 17.23 !True EOS critical point [K, mol/L] (where dP/dD=0 and d^2P/dD^2=0 at constant T)
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:DOI: 10.1063/1.4864752
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Richardson, I.A., Leachman, J.W., and Lemmon, E.W.,
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? J. Phys. Chem. Ref. Data, 43(1), 013103, 2014.
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?
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?The uncertainty in density is 0.5% over the full temperature and pressure ranges
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? of validity of the equation of state. The uncertainties in vapor pressure and
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? saturated liquid density are 2% and 3%, respectively, while speed-of-sound
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? values have an uncertainty of 1% in the liquid phase.
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?
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!```````````````````````````````````````````````````````````````````````````````
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18.724 !Lower temperature limit [K]
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600.0 !Upper temperature limit [K]
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2000000.0 !Upper pressure limit [kPa]
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43.351 !Maximum density [mol/L]
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CPP !Pointer to Cp0 model
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4.0282 !Molar mass [g/mol]
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18.724 !Triple point temperature [K]
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17.189 !Pressure at triple point [kPa]
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43.351 !Density at triple point [mol/L]
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23.661 !Normal boiling point temperature [K]
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-0.136 !Acentric factor
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38.34 1679.6 17.23 !Tc [K], pc [kPa], rhoc [mol/L]
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38.34 17.23 !Reducing parameters [K, mol/L]
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8.3144598 !Gas constant [J/mol-K]
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14 4 7 12 0 0 0 0 0 0 0 0 !# terms and # coefs/term for normal terms, Gaussian terms, and Gao terms
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0.006267958 1.0 4. 0. !a(i),t(i),d(i),l(i)
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10.53609 0.462 1. 0.
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-10.14149 0.5584 1. 0.
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0.3560610 0.627 2. 0.
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0.1824472 1.201 3. 0.
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-1.129638 0.309 1. 0.
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-0.0549812 1.314 3. 0.
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-0.6791329 1.1166 2. 0.
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1.347918 1.25 2. 1.
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-0.8657582 1.25 2. 1.
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1.719146 1.395 1. 2.
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-1.917977 1.627 1. 2.
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0.1233365 1.0 3. 2.
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-0.07936891 2.5 2. 2.
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1.686617 0.635 1. 2. 2. -0.868 -0.613 0.6306 1.460 0. 0. 0.
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-4.240326 0.664 1. 2. 2. -0.636 -0.584 0.7110 1.7864 0. 0. 0.
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1.857114 0.7082 2. 2. 2. -0.668 -0.570 0.6446 1.647 0. 0. 0.
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-0.5903705 2.25 3. 2. 2. -0.650 -1.056 0.8226 0.541 0. 0. 0.
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1.520171 1.524 3. 2. 2. -0.745 -1.010 0.9920 0.969 0. 0. 0.
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2.361373 0.67 1. 2. 2. -0.782 -1.025 1.2184 1.892 0. 0. 0.
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-2.297315 0.709 3. 2. 2. -0.693 -1.029 1.2030 1.076 0. 0. 0.
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eta beta gamma epsilon
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EXP[eta*(delta-epsilon)^2+beta*(tau-gamma)^2]
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#AUX !---Auxiliary function for Cp0
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CPP !Ideal gas heat capacity function for deuterium of Richardson et al. (2014).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Richardson, I.A., Leachman, J.W., and Lemmon, E.W., 2014.
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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1.0 8.3144598 !Reducing parameters for T, Cp0
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1 12 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
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2.5 0.0
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-3.54145 7174.1
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3.0326 8635.0
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-3.52422 902.7
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-1.73421 181.1
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-3.57135 438.5
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2.14858 5034.2
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6.23107 269.9
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-3.30425 229.9
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6.23098 666.4
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-3.57137 452.8
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3.32901 192.0
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0.97782 1187.6
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#AUX !---Auxiliary function for PX0
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PX0 !Helmholtz energy ideal-gas function for deuterium of Richardson et al. (2014).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Richardson, I.A., Leachman, J.W., and Lemmon, E.W., 2014.
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?
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!```````````````````````````````````````````````````````````````````````````````
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1 2 12 0 0 0 0 0 !Nterms: ai*log(tau**ti); ai*tau**ti; ai*log(1-exp(bi*tau))
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1.5 1.0 !ai, ti for [ai*log(tau**ti)] terms
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-2.0677350466039846 0.0 !aj, ti for [ai*tau**ti] terms
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2.4237150686246927 1.0 !aj, ti for [ai*tau**ti] terms
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-3.54145 7174.1 !aj, ti for [ai*log(1-exp(-ti/T)] terms
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3.0326 8635.0
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-3.52422 902.7
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-1.73421 181.1
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-3.57135 438.5
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2.14858 5034.2
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6.23107 269.9
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-3.30425 229.9
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6.23098 666.4
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-3.57137 452.8
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3.32901 192.0
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0.97782 1187.6
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#AUX !---Auxiliary function for PH0
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PH0 !Ideal gas Helmholtz form for deuterium.
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Richardson, I.A., Leachman, J.W., and Lemmon, E.W., 2014.
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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1 2 12 0 0 0 0 0 !Nterms: ai*log(tau**ti); ai*tau**ti; ai*log(1-exp(bi*tau)); cosh; sinh
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1.5 1.0 !ai, ti for [ai*log(tau**ti)] terms
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-2.0677351753 0.0 !aj, ti for [ai*tau**ti] terms
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2.4237151502 1.0
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-3.54145 -187.1178925404 !aj, ti for [ai*log(1-exp(ti*tau)] terms
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3.0326 -225.2217005738
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-3.52422 -23.544600939
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-1.73421 -4.7235263432
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-3.57135 -11.4371413667
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2.14858 -131.3041210224
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6.23107 -7.0396452791
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-3.30425 -5.9963484611
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6.23098 -17.381324987
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-3.57137 -11.8101199791
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3.32901 -5.0078247261
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0.97782 -30.9754825248
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--------------------------------------------------------------------------------
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@EOS !---Equation of state---
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BWR !MBWR equation of state for deuterium of McCarty (1989).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?McCarty, R.D.,
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? "Correlations for the Thermophysical Properties of Deuterium,"
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? unpublished correlation.
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? National Institute of Standards and Technology, Boulder, CO, 1989.
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? All temperatures on IPTS-68.
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?
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!```````````````````````````````````````````````````````````````````````````````
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18.71 !Lower temperature limit [K]
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423.0 !Upper temperature limit [K]
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320000.0 !Upper pressure limit [kPa]
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43.38 !Maximum density [mol/L]
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CP1 !Pointer to Cp0 model
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4.0282 !Molar mass [g/mol]
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18.71 !Triple point temperature [K]
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19.462 !Pressure at triple point [kPa]
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43.365 !Density at triple point [mol/L]
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23.3097 !Normal boiling point temperature [K]
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-0.175 !Acentric factor
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38.34 1665.3 17.327 !Tc [K], pc [kPa], rhoc [mol/L]
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38.34 17.327 !Reducing parameters [K, mol/L]
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17.3279988559019 !gamma
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0.0831434 !Gas constant [L-bar/mol-K]
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32 1 !Nterm, Ncoeff per term
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0.4894244053982e-4 0.05600164604601 -0.6301493491211
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2.538329946038 172.3475985309 0.2956238369436e-4
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-0.003926317169317 0.01195764193293 11369.16678824
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-0.1916378195727e-6 0.0003153535946452 0.0212293733507
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-0.1057999371607e-5 -0.6722062598854e-4 -0.3030166828627
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0.1980817195099e-5 -0.1453922641871e-7 0.0001780919116891
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-0.1823145348424e-5 -11353.58616578 -1943.542941899
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-36.3284766958 108.774511838 -0.04078276062687
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0.006460021864005 -0.4480242189217e-4 -0.0002475011206216
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-0.883438465676e-8 -0.1081622159862e-8 -0.1478159334303e-10
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0.7926922356112e-11 0.5721547329378e-11
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@AUX !---Auxiliary function for Cp0
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CP1 !Ideal gas heat capacity function for deuterium.
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?
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?```````````````````````````````````````````````````````````````````````````````
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?refit by EWL from calculations of piecewise fit of Cp0 by McCarty
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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1.0 8.31434 !Reducing parameters for T, Cp0
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6 3 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
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2.4512991 0.0
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0.0043563077 1.0
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-0.0005316947 1.5
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0.000017067184 2.0
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-0.53819932e-8 3.0
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0.89310438e-12 4.0
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18.403263 319.0
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-21.257617 361.0
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4.1091635 518.0
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^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^
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#ETA !---Viscosity---
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VS7 !Pure fluid viscosity model from symbolic regression for deuterium of Muzny et al. (2013).
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:DOI: 10.1021/je301273j
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Muzny, C.D., Huber, M.L., and Kazakov, A.F.,
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? "Correlation for the Viscosity of Normal Hydrogen Obtained from Symbolic Regression,"
|
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? J. Chem. Eng. Data, 58:969-979, 2013.
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?
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?The uncertainties for deuterium are estimated to be approximately 5% in the gas and
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? supercritical regions with larger deviations near the critical region and in the liquid phase.
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?
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!```````````````````````````````````````````````````````````````````````````````
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18.724 !Lower temperature limit [K]
|
||||
600.0 !Upper temperature limit [K]
|
||||
2000000.0 !Upper pressure limit [kPa]
|
||||
43.351 !Maximum density [mol/L]
|
||||
NUL !Pointer to collision integral model
|
||||
!
|
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!Dilute gas function
|
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$DG RED SUMLOGT:5 EXP CNST SQR * INV SUM:1 CNST * SQRT * CNST SQRT *
|
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!
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!Second viscosity virial function
|
||||
$VV RED SUM:7 CNST CUBE *
|
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!
|
||||
!Residual function
|
||||
$RF RED SUM:3 SUM:1 SUM:2 / + EXP SUM:1 * CNST *
|
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!
|
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!Coefficients
|
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$CF
|
||||
0.021357 30.41 1. 0. 0 !Reducing parameters for eta, T, rho
|
||||
0.209630 0. 0. 0. 0 ! s1*LOG(Ts) Coefficient to match Moldover
|
||||
-0.455274 1. 0. 0. 0 ! s2*LOG(Ts)
|
||||
0.143602 2. 0. 0. 0 ! s3*LOG(Ts)^2
|
||||
-0.0335325 3. 0. 0. 0 ! s4*LOG(Ts)^3
|
||||
0.00276981 4. 0. 0. 0 ! s5*LOG(Ts)^4
|
||||
0.297 0. 0. 0. 0 ! e3^2*EXP(above)
|
||||
2.01588 1. 0. 0. 0 ! e2*T (use below)
|
||||
30.41 0. 0. 0. 0 ! SQRT(e2*T*Tred)
|
||||
2. 0. 0. 0. 0 ! SQRT(2) for deuterium
|
||||
!Virial terms
|
||||
0.6022137 30.41 1. 0. 0 !Reducing parameters for eta, T, rho
|
||||
-0.187 0. 0. 0. 0 ! b2
|
||||
2.4871 -1. 0. 0. 0 ! b3/Ts
|
||||
3.7151 -2. 0. 0. 0 ! b4/Ts^2
|
||||
-11.0972 -3. 0. 0. 0 ! b5/Ts^3
|
||||
9.0965 -4. 0. 0. 0 ! b6/Ts^4
|
||||
-3.8292 -5. 0. 0. 0 ! b7/Ts^5
|
||||
0.5166 -6. 0. 0. 0 ! b8/Ts^6
|
||||
0.297 0. 0. 0. 0 ! b9^3*sum(above)
|
||||
!Residual function terms.
|
||||
1000. 33.145 45.096479408 0. 0 !Reducing parameters for eta, T, rho
|
||||
0.0456334068 1. 0. 0. 0 ! a2*Tr
|
||||
0.232797868 -1. 0. 0. 0 ! a3/Tr
|
||||
0.363576595 0. 6. 0. 0 ! a6*Dr^6
|
||||
0.958326120 0. 2. 0. 0 ! a4*Dr^2
|
||||
0.127941189 0. 0. 0. 0 ! a5
|
||||
1.0 1. 0. 0. 0 ! [a4*Dr^2 from above]/(a5+Tr)
|
||||
0.00643449673 0. 2. 0. 0 ! a1*Dr^2*EXP(above)
|
||||
1.18 0. 0. 0. 0 ! *1.18 for deuterium
|
||||
NUL !Pointer to the viscosity critical enhancement auxiliary function (none used)
|
||||
|
||||
|
||||
|
||||
|
||||
================================================================================
|
||||
|
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#TCX !---Thermal conductivity---
|
||||
TC1 !Pure fluid thermal conductivity model for deuterium of Assael et al. (2011).
|
||||
:DOI: 10.1063/1.3606499
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?unpublished; based on scaling the Assael correlation:
|
||||
? Assael, M.J., Assael, J.-A.M., Huber, M.L., Perkins, R.A., and Takata, Y.,
|
||||
? "Correlation of the Thermal Conductivity of Normal and Parahydrogen
|
||||
? from the Triple Point to 1000 K and up to 100 MPa,"
|
||||
? J. Phys. Chem. Ref. Data, 40(3):1-13, 2011.
|
||||
?
|
||||
?The uncertainties for deuterium are estimated to be approximately 5% in the gas
|
||||
? and supercritical regions with larger deviations near the critical region and
|
||||
? in the liquid phase.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
18.724 !Lower temperature limit [K]
|
||||
600.0 !Upper temperature limit [K]
|
||||
2000000.0 !Upper pressure limit [kPa]
|
||||
43.351 !Maximum density [mol/L]
|
||||
7 4 !# terms for dilute gas function: numerator, denominator
|
||||
1.0 0.001 !Reducing parameters for T, tcx dilute gas divided by sqrt2
|
||||
-8779370. 0.
|
||||
3564210. 1.
|
||||
-34002.5 2.
|
||||
230.795 3.
|
||||
0.0676148 4.
|
||||
1.22675e-4 5.
|
||||
-2.21184e-8 6.
|
||||
5043050. 0.
|
||||
-24375.3 1.
|
||||
151.523 2.
|
||||
1.0 3.
|
||||
10 0 !# terms for background gas function: numerator, denominator
|
||||
33.145 15.508 1. !Reducing parameters for T, rho, tcx
|
||||
0.0363081 0. 1. 0.
|
||||
-0.0207629 0. 2. 0.
|
||||
0.031481 0. 3. 0.
|
||||
-0.0143097 0. 4. 0.
|
||||
0.0017498 0. 5. 0.
|
||||
0.0018337 1. 1. 0.
|
||||
-0.00886716 1. 2. 0.
|
||||
0.015826 1. 3. 0.
|
||||
-0.0106283 1. 4. 0.
|
||||
0.00280673 1. 5. 0.
|
||||
TK3 !Pointer to critical enhancement auxiliary function
|
||||
|
||||
|
||||
#AUX !---Auxiliary function for the thermal conductivity critical enhancement
|
||||
TK3 !Simplified thermal conductivity critical enhancement for deuterium of Assael et al. (2011).
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?Assael, M.J., Assael, J.-A.M., Huber, M.L., Perkins, R.A., and Takata, Y., 2011.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
0. !
|
||||
10000. !
|
||||
0. !
|
||||
0. !
|
||||
9 0 0 0 !# terms: terms, spare, spare, spare
|
||||
1.0 1.0 1.0 !Reducing parameters for T, rho, tcx [mW/(m-K)]
|
||||
0.63 !Nu (universal exponent)
|
||||
1.2415 !Gamma (universal exponent)
|
||||
1.01 !R0 (universal amplitude)
|
||||
0.065 !Z (universal exponent--not used for t.c., only viscosity)
|
||||
1.0 !C (constant in viscosity eqn = 1/[2 - (alpha + gamma)/(2*nu)], but often set to 1)
|
||||
0.15e-9 !Xi0 (amplitude) [m]
|
||||
0.052 !Gam0 (amplitude) [-]
|
||||
0.4e-9 !Qd_inverse (modified effective cutoff parameter) [m]
|
||||
57.51 !Tref (reference temperature) [K]
|
||||
|
||||
|
||||
|
||||
|
||||
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
|
||||
|
||||
@TRN !---ECS Transport---
|
||||
ECS !Extended Corresponding States model (Nitrogen reference); fit to limited data for deuterium.
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?*** ESTIMATION METHOD *** NOT STANDARD REFERENCE QUALITY ***
|
||||
?Unpublished; uses method described in the following reference:
|
||||
?Huber, M.L., Laesecke, A., and Perkins, R.A.
|
||||
? "Model for the Viscosity and Thermal Conductivity of Refrigerants, Including
|
||||
? a New Correlation for the Viscosity of R134a,"
|
||||
? Ind. Eng. Chem. Res., 42(13):3163-3178, 2003. doi: 10.1021/ie0300880
|
||||
?
|
||||
?Estimated uncertainty is 50%.
|
||||
?
|
||||
?The Lennard-Jones parameters were taken from Kestin, J. and Nagashima, A.,"Viscosity of the isotopes of hydrogen and their interatomic force potentials", Physics of Fluids, 7:730-734 (1964).
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
18.724 !Lower temperature limit [K]
|
||||
600.0 !Upper temperature limit [K]
|
||||
2000000.0 !Upper pressure limit [kPa]
|
||||
43.351 !Maximum density [mol/L]
|
||||
FEQ NITROGEN.FLD
|
||||
VS1 !Model for reference fluid viscosity
|
||||
TC1 !Model for reference fluid thermal conductivity
|
||||
NUL !Large molecule identifier
|
||||
1 !Lennard-Jones flag (0 or 1) (0 => use estimates)
|
||||
0.2952 !Lennard-Jones coefficient sigma [nm]
|
||||
35.2 !Lennard-Jones coefficient epsilon/kappa [K]
|
||||
1 0 0 !Number of terms in f_int term in Eucken correlation, spare1, spare2
|
||||
0.00132 0. 0. 0. !Coefficient, power of T, spare1, spare2
|
||||
1 0 0 !Number of terms in psi (visc shape factor): poly,spare1,spare2
|
||||
1.0 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
|
||||
1 0 0 !Number of terms in chi (t.c. shape factor): poly,spare1,spare2
|
||||
1.0 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
|
||||
TK3 !Pointer to critical enhancement auxiliary function
|
||||
|
||||
|
||||
|
||||
|
||||
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
|
||||
|
||||
#STN !---Surface tension---
|
||||
ST1 !Surface tension model for deuterium of Mulero et al. (2012).
|
||||
:DOI: 10.1063/1.4768782
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?Mulero, A., Cachadiña, I., and Parra, M.I.,
|
||||
? "Recommended Correlations for the Surface Tension of Common Fluids,"
|
||||
? J. Phys. Chem. Ref. Data, 41(4), 043105, 2012. doi: 10.1063/1.4768782
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
0. !
|
||||
10000. !
|
||||
0. !
|
||||
0. !
|
||||
1 !Number of terms in surface tension model
|
||||
38.34 !Critical temperature used in fit (dummy)
|
||||
0.009376 1.258 !Sigma0 and n
|
||||
|
||||
|
||||
#PS !---Vapor pressure---
|
||||
PS5 !Vapor pressure equation for deuterium of Richardson et al. (2014).
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc
|
||||
? are the reducing parameters below, which are followed by rows containing Ni and ti.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
0. !
|
||||
10000. !
|
||||
0. !
|
||||
0. !
|
||||
38.34 1679.6 !Reducing parameters
|
||||
5 0 0 0 0 0 !Number of terms in equation
|
||||
-5.5706 1.0
|
||||
1.7631 1.5
|
||||
-0.5458 2.83
|
||||
1.2154 4.06
|
||||
-1.1556 5.4
|
||||
|
||||
|
||||
#DL !---Saturated liquid density---
|
||||
DL1 !Saturated liquid density equation for deuterium of Richardson et al. (2014).
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?Functional Form: D=Dc*[1+SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
|
||||
? the reducing parameters below, which are followed by rows containing Ni and ti.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
0. !
|
||||
10000. !
|
||||
0. !
|
||||
0. !
|
||||
38.34 17.23 !Reducing parameters
|
||||
6 0 0 0 0 0 !Number of terms in equation
|
||||
3.3769 0.512
|
||||
-5.3693 1.12
|
||||
11.943 1.8
|
||||
-17.361 2.55
|
||||
15.170 3.4
|
||||
-6.3079 4.4
|
||||
|
||||
|
||||
#DV !---Saturated vapor density---
|
||||
DV3 !Saturated vapor density equation for deuterium of Richardson et al. (2014).
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?Functional Form: D=Dc*EXP[SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
|
||||
? the reducing parameters below, which are followed by rows containing Ni and ti.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
0. !
|
||||
10000. !
|
||||
0. !
|
||||
0. !
|
||||
38.34 17.23 !Reducing parameters
|
||||
6 0 0 0 0 0 !Number of terms in equation
|
||||
-3.8111 0.528
|
||||
-7.3624 2.03
|
||||
2.2294 3.6
|
||||
-21.443 5.0
|
||||
12.796 6.5
|
||||
-31.334 9.0
|
||||
|
||||
|
||||
@END
|
||||
c 1 2 3 4 5 6 7 8
|
||||
c2345678901234567890123456789012345678901234567890123456789012345678901234567890
|
||||
0.2948 !Lennard-Jones coefficient sigma [nm] for ECS method
|
||||
39.3 !Lennard-Jones coefficient epsilon/kappa [K] for ECS method
|
||||
|
||||
|
||||
@ETA !Viscosity model specification
|
||||
VS0 pure fluid viscosity model of Muzny et al. (2013).
|
||||
?
|
||||
?```````````````````````````````````````````````````````````````````````````````
|
||||
?unpublished; based on scaling the Muzny hydrogen correlation
|
||||
? Muzny, C.D., Huber, M.L., and Kazakov, A.F.,
|
||||
? "Correlation for the Viscosity of normal hydrogen obtained from symbolic regression"
|
||||
? submitted to J. Chem. Eng. Data, 2013
|
||||
?
|
||||
?The uncertainties for deuterium are estimated to be approximately 5% in the gas and supercritical regions
|
||||
? with larger deviations near the critical region and in the liquid phase.
|
||||
?
|
||||
!```````````````````````````````````````````````````````````````````````````````
|
||||
18.724 !Lower temperature limit [K]
|
||||
600.0 !Upper temperature limit [K]
|
||||
2000000.0 !Upper pressure limit [kPa]
|
||||
43.351 !Maximum density [mol/L]
|
||||
D2 !Pointer to hardcoded thermal conductivity model
|
||||
0 1 1 0 0 0 0 0 !Number of terms for various pieces
|
||||
1. 1. 1. !Reducing parameters for T, rho, eta
|
||||
0. 0. 0. 0. 0 !Dilute gas coeffs
|
||||
0. 0. 0. 0. 0 !Residual coeffs
|
||||
NUL !Pointer to the viscosity critical enhancement auxiliary function (none used)
|
||||
Reference in New Issue
Block a user