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一些优化：CAN和PLC地址的优化

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Fluorine !Short name
7782-41-4 !CAS number
Fluorine !Full name
F2 !Chemical formula {F2}
Fluorine !Synonym
37.99681 !Molar mass [g/mol]
53.4811 !Triple point temperature [K]
85.0368 !Normal boiling point [K]
144.414 !Critical temperature [K]
5172.4 !Critical pressure [kPa]
15.603 !Critical density [mol/L]
0.0449 !Acentric factor
0.0 !Dipole moment [Debye]; (exactly zero due to symmetry)
NBP !Default reference state
10.0 !Version number
1045 !UN Number :UN:
cryogen !Family :Family:
0.0 !Heating value (upper) [kJ/mol] :Heat:
1S/F2/c1-2 !Standard InChI String :InChi:
PXGOKWXKJXAPGV-UHFFFAOYSA-N !Standard InChI Key :InChiKey:
edbdc8e0 (nitrogen) !Alternative fluid for mixing rules :AltID:
cdc99fe0 !Hash number from InChI Key :Hash:
!The fluid files contain general information about the fluid in the first 15 to 20 lines, followed by sections for the
! equations of state, transport equations, and auxiliary equations. Equations of state are listed first. The NIST recommended
! equations begin with a hash mark (#). The secondary equations begin with the @ symbol. These symbols can be swapped to
! select a secondary equation as primary and the primary as secondary. The equation of state section also contains auxiliary
! equations for the ideal gas heat capacity or ideal gas Helmholtz energy. Below the equations of state (both primary and
! secondary) are the transport equations, first viscosity and then thermal conductivity. These are then followed by the
! secondary equations if available. The transport section also contains auxiliary equations required to calculate either the
! dilute gas state or the critical enhancement. At the end of the file are additional but not necessary auxiliary equations,
! including simple equations for the vapor pressure, saturated liquid and vapor densities, melting line (for some fluids), and
! sublimation line (for even fewer fluids). This section also contains the equations for dielectric constant and surface
! tension if available. The sections are divided by different symbols (these being _-+=^*~) to aid the eye in locating a
! particular section. Secondary equations are indented 10 spaces to avoid confusion with the NIST recommended equations. The
! end of the fluid file is marked with @END. Anything below that is ignored.
! compiled by E.W. Lemmon, NIST Physical and Chemical Properties Division, Boulder, Colorado
! 04-06-98 EWL, Original version.
! 11-18-98 EWL, Add equation of state of Polt et al. (1992).
! 06-21-10 CKL, Add ancillary equations.
! 07-09-10 MLH, Add predictive model based on Hanley (1972) recommended values.
! 12-06-12 EWL, Add surface tension coefficients of Mulero et al. (2012).
! 11-22-17 MLH, Revise transport.
! 02-28-18 IHB, Add sublimation line model.
________________________________________________________________________________
#EOS !---Equation of state---
FEQ !Helmholtz equation of state for fluorine of de Reuck (1990).
:TRUECRITICALPOINT: 144.414 15.603 !True EOS critical point [K, mol/L] (where dP/dD=0 and d^2P/dD^2=0 at constant T)
:DOI:
?
?```````````````````````````````````````````````````````````````````````````````
?de Reuck, K.M.,
? "International Thermodynamic Tables of the Fluid State-11 Fluorine,"
? International Union of Pure and Applied Chemistry, Pergamon Press,
? Oxford, 1990.
?
?The uncertainties of the equation of state are 0.2% in density, 2% in heat
? capacity, and 1.5% in the speed of sound, except in the critical region.
?
!```````````````````````````````````````````````````````````````````````````````
53.4811 !Lower temperature limit [K]
300.0 !Upper temperature limit [K]
20000.0 !Upper pressure limit [kPa]
45.47 !Maximum density [mol/L]
CPP !Pointer to Cp0 model
37.99681 !Molar mass [g/mol]
53.4811 !Triple point temperature [K]
0.23881 !Pressure at triple point [kPa]
44.917 !Density at triple point [mol/L]
85.0368 !Normal boiling point temperature [K]
0.0449 !Acentric factor
144.414 5172.4 15.603 !Tc [K], pc [kPa], rhoc [mol/L]
144.414 15.603 !Reducing parameters [K, mol/L]
8.31448 !Gas constant [J/mol-K]
31 5 0 0 0 0 0 0 0 0 0 0 !# terms and # coefs/term for normal terms, Gaussian terms, and Gao terms
1.51144749736 0.0 1. 0. 0. !a(i),t(i),d(i),l(i)
-2.98666288409 0.5 1. 0. 0.
3.29644905098 1.5 1. 0. 0.
-2.98458624201 2.0 1. 0. 0.
-2.28688966459 0.5 2. 0. 0.
-1.094921934 1.0 2. 0. 0.
3.04775277572 0.5 3. 0. 0.
0.115689564208 2.0 3. 0. 0.
-1.16100171627 0.5 4. 0. 0.
0.295656394476 1.0 4. 0. 0.
0.0711482542928 0.0 5. 0. 0.
-0.00171363832155 0.5 8. 0. 0.
0.000665317955515 0.0 9. 0. 0.
5.06026676251 1.0 2. 2. 1.07810258
-6.2926843544 3.0 2. 2. 1.07810258
6.17784808739 4.0 2. 2. 1.07810258
-1.55366191788 5.0 2. 2. 1.07810258
-2.87170687343 1.0 3. 2. 1.07810258
3.17214480494 4.0 3. 2. 1.07810258
-2.67969025215 5.0 3. 2. 1.07810258
2.71865479252 1.0 4. 2. 1.07810258
-1.07191065039 3.0 4. 2. 1.07810258
1.26597342291 5.0 4. 2. 1.07810258
-0.706244695489 4.0 5. 2. 1.07810258
0.268707888826 4.0 6. 2. 1.07810258
0.0527251190274 1.0 7. 2. 1.07810258
0.0544411481926 1.0 8. 2. 1.07810258
0.000228949994105 5.0 12. 2. 1.07810258
-0.547908264304e-9 30.0 4. 2. 2.15620515
-0.096427322495 20.0 6. 2. 3.23430773
0.000368084486225 25.0 6. 2. 3.23430773
#AUX !---Auxiliary function for Cp0
CPP !Ideal gas heat capacity function for fluorine of de Reuck (1990).
?
?```````````````````````````````````````````````````````````````````````````````
?de Reuck, K.M., 1990.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
144.414 8.31448 !Reducing parameters for T, Cp0
4 1 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
3.5011231 0.0
-0.000060936946 4.0
0.0006319669 3.0
-0.000074069617 -2.0
1.012767 1286.12
#AUX !---Auxiliary function for PX0
PX0 !Helmholtz energy ideal-gas function for fluorine of de Reuck (1990).
?
?```````````````````````````````````````````````````````````````````````````````
?de Reuck, K.M., 1990.
?
!```````````````````````````````````````````````````````````````````````````````
1 5 1 0 0 0 0 0 !Nterms: ai*log(tau**ti); ai*tau**ti; ai*log(1-exp(bi*tau))
2.5011231 1.0 !ai, ti for [ai*log(tau**ti)] terms
-3.5816391237711436 0.0 !aj, ti for [ai*tau**ti] terms
3.5221357998979133 1.0 !aj, ti for [ai*tau**ti] terms
-0.140101729176e-12 -4.0
0.209829449040e-09 -3.0
-0.154475174192e+01 2.0
1.012767 1286.12 !aj, ti for [ai*log(1-exp(-ti/T)] terms
#AUX !---Auxiliary function for PH0
PH0 !Ideal gas Helmholtz form for fluorine.
?
?```````````````````````````````````````````````````````````````````````````````
?de Reuck, K.M., 1990.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
1 5 1 0 0 0 0 0 !Nterms: ai*log(tau**ti); ai*tau**ti; ai*log(1-exp(bi*tau)); cosh; sinh
2.5011231 1.0 !ai, ti for [ai*log(tau**ti)] terms
-3.5816408414 0.0 !aj, ti for [ai*tau**ti] terms
3.5221368165 1.0
0.0000030468 -4.0
-0.0000526639 -3.0
0.0000370348 2.0
1.012767 -8.9057847577 !aj, ti for [ai*log(1-exp(ti*tau)] terms
--------------------------------------------------------------------------------
@EOS !---Equation of state---
FE2 !Helmholtz equation of state for fluorine of Polt et al. (1992).
?
?```````````````````````````````````````````````````````````````````````````````
?Polt, A., Platzer, B., and Maurer, G.,
? "Parameter der thermischen Zustandsgleichung von Bender fuer 14
? mehratomige reine Stoffe,"
? Chem. Tech. (Leipzig), 44(6):216-224, 1992.
?
!```````````````````````````````````````````````````````````````````````````````
53.4811 !Lower temperature limit [K]
300.0 !Upper temperature limit [K]
25000.0 !Upper pressure limit [kPa]
45.14 !Maximum density [mol/L]
CP1 !Pointer to Cp0 model
37.997 !Molar mass [g/mol]
53.4811 !Triple point temperature [K]
0.25394 !Pressure at triple point [kPa]
44.890 !Density at triple point [mol/L]
84.947 !Normal boiling point temperature [K]
0.0449 !Acentric factor
144.31 5215.3 15.106456 !Tc [K], pc [kPa], rhoc [mol/L]
144.31 15.106456 !Reducing parameters [K, mol/L]
8.3143 !Gas constant [J/mol-K]
22 5 0 0 0 0 0 0 0 0 0 0 !# terms and # coefs/term for normal terms, Gaussian terms, and Gao terms
0.00862212325175 3. 0. 0. 0. !a(i),t(i),d(i),l(i)
0.162286882091 4. 0. 0. 0.
-0.0228707299586 5. 0. 0. 0.
0.624951179331 0. 1. 0. 0.
-1.58918489879 1. 1. 0. 0.
0.195171867807 2. 1. 0. 0.
-0.438453517535 3. 1. 0. 0.
0.0402200928405 4. 1. 0. 0.
0.0319444405579 0. 2. 0. 0.
0.0161784325978 1. 2. 0. 0.
0.230132378392 2. 2. 0. 0.
0.0819206229044 0. 3. 0. 0.
-0.173741828076 1. 3. 0. 0.
0.0137942204542 0. 4. 0. 0.
-0.00449971813506 1. 4. 0. 0.
0.0075655466178 1. 5. 0. 0.
-0.00862212325175 3. 0. 2. 0.9225328
-0.162286882091 4. 0. 2. 0.9225328
0.0228707299586 5. 0. 2. 0.9225328
0.184612089745 3. 2. 2. 0.9225328
-0.425779777811 4. 2. 2. 0.9225328
0.0825656492996 5. 2. 2. 0.9225328
@AUX !---Auxiliary function for Cp0
CP1 !Ideal gas heat capacity function for fluorine.
?
?```````````````````````````````````````````````````````````````````````````````
?Polt, A., Platzer, B., and Maurer, G.,
? "Parameter der thermischen Zustandsgleichung von Bender fuer 14
? mehratomige reine Stoffe,"
? Chem. Tech. (Leipzig), 44(6):216-224, 1992.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
1.0 37.997 !Reducing parameters for T, Cp0
5 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
0.7593432 0.0
0.0002883653 1.0
-0.000004192916 2.0
0.2309778e-7 3.0
-3.291582e-11 4.0
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
#TRN !---ECS Transport---
ECS !Extended Corresponding States model (Propane reference); predictive mode for fluorine.
:DOI: 10.6028/NIST.IR.8209
?
?```````````````````````````````````````````````````````````````````````````````
?*** ESTIMATION METHOD *** NOT STANDARD REFERENCE QUALITY ***
?Huber, M.L., "Models for the Viscosity, Thermal Conductivity, and Surface Tension
? of Selected Pure Fluids as Implemented in REFPROP v10.0," NISTIR 8209, 2018.
? doi: 10.6028/NIST.IR.8209
?
?Based on predicted values of Hanley, H.J.M., and Prydz, R., "The Viscosity and Thermal Conductivity Coefficients of Gaseous and Liquid Fluorine," J. Phys. Chem. Ref. Data, 1(4):1101-1113, 1972.
?
?Estimated uncertainty for viscosity: 20%.
?Estimated uncertainty for thermal conductivity: 20%.
?
?The Lennard-Jones parameters were taken from Reid, R.C., Prausnitz, J.M., and Poling, B.E., "The Properties of Gases and Liquids," 4th edition, New York, McGraw-Hill Book Company, 1987.
?
!```````````````````````````````````````````````````````````````````````````````
53.4811 !Lower temperature limit [K]
300.0 !Upper temperature limit [K]
20000.0 !Upper pressure limit [kPa]
45.47 !Maximum density [mol/L]
FEQ PROPANE.FLD
VS1 !Model for reference fluid viscosity
TC1 !Model for reference fluid thermal conductivity
BIG !Large molecule identifier
0.97 0. 0. 0. !Large molecule parameters
1 !Lennard-Jones flag (0 or 1) (0 => use estimates)
0.3357 !Lennard-Jones coefficient sigma [nm]
112.6 !Lennard-Jones coefficient epsilon/kappa [K]
1 0 0 !Number of terms in f_int term in Eucken correlation, spare1, spare2
0.00105 0. 0. 0. !Coefficient, power of T, spare1, spare2
3 0 0 !Number of terms in psi (visc shape factor): poly,spare1,spare2
1.8426 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
-0.748356 0. 1. 0. !Coefficient, power of Tr, power of Dr, spare
0.16319 0. 2. 0. !Coefficient, power of Tr, power of Dr, spare
2 0 0 !Number of terms in chi (t.c. shape factor): poly,spare1,spare2
0.753172 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
6.58443e-2 0. 1. 0. !Coefficient, power of Tr, power of Dr, spare
TK3 !Pointer to critical enhancement auxiliary function
#AUX !---Auxiliary function for the thermal conductivity critical enhancement
TK3 !Simplified thermal conductivity critical enhancement for fluorine of Perkins et al. (2013).
?
?```````````````````````````````````````````````````````````````````````````````
?Perkins, R.A., Sengers, J.V., Abdulagatov, I.M., and Huber, M.L.,
? "Simplified Model for the Critical Thermal-Conductivity Enhancement in Molecular Fluids,"
? Int. J. Thermophys., 34(2):191-212, 2013. doi: 10.1007/s10765-013-1409-z
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
9 0 0 0 !# terms: CO2-terms, spare, spare, spare
1.0 1.0 1.0 !Reducing parameters for T, rho, tcx [mW/(m-K)]
0.63 !Nu (universal exponent)
1.239 !Gamma (universal exponent)
1.02 !R0 (universal amplitude)
0.063 !Z (universal exponent--not used for t.c., only viscosity)
1.0 !C (constant in viscosity eqn = 1/[2 - (alpha + gamma)/(2*nu)], but often set to 1)
0.145e-9 !Xi0 (amplitude) [m]
0.056 !Gam0 (amplitude) [-]
0.385e-9 !Qd_inverse (modified effective cutoff parameter) [m]; estimated-not fitted to data
216.621 !Tref (reference temperature)=1.5*Tc [K]
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
#STN !---Surface tension---
ST1 !Surface tension model for fluorine of Mulero et al. (2012).
:DOI: 10.1063/1.4768782
?
?```````````````````````````````````````````````````````````````````````````````
?Mulero, A., Cachadiña, I., and Parra, M.I.,
? "Recommended Correlations for the Surface Tension of Common Fluids,"
? J. Phys. Chem. Ref. Data, 41(4), 043105, 2012. doi: 10.1063/1.4768782
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
1 !Number of terms in surface tension model
144.414 !Critical temperature used in fit (dummy)
0.03978 1.218 !Sigma0 and n
#MLT !---Melting line---
ML1 !Melting line model for fluorine of de Reuck (1990).
:DOI:
?
?```````````````````````````````````````````````````````````````````````````````
?de Reuck, K.M., 1990.
?
!```````````````````````````````````````````````````````````````````````````````
53.4811 !Lower temperature limit [K]
300.0 !Upper temperature limit [K]
0. !
0. !
53.4811 1000. !Reducing temperature and pressure
3 0 0 0 0 0 !Number of terms in melting line equation
0.000252 0.0 !Coefficients and exponents
249.975 2.1845
-249.9750131 0.0
#SBL !---Sublimation line---
SB2 !Sublimation line model for fluorine of Brown and Zeigler (2009).
:DOI: 10.1007/978-1-4613-9856-1_76
?
?```````````````````````````````````````````````````````````````````````````````
?Based on G.N. Brown and W.T. Ziegler, Adv. Cryo. Eng., 25:662-670, 1979.
? Modified to match the triple point of the equation of state.
?
!```````````````````````````````````````````````````````````````````````````````
53.4811 !Lower temperature limit [K]
90.368 !Upper temperature limit [K]
0. !
0. !
1.0 1000.0 !Reducing temperature and pressure
4 0 0 0 0 0 !Number of terms in sublimation line equation
10.0252 0.0 !Coefficients and exponents
-7.1089e2 -1.0
-1.0167e4 -2.0
1.2001e5 -3.0
#PS !---Vapor pressure---
PS5 !Vapor pressure equation for fluorine of Lemmon (2010).
?
?```````````````````````````````````````````````````````````````````````````````
?Lemmon, C.K. and Lemmon, E.W., 2010.
?
?Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc
? are the reducing parameters below, which are followed by rows containing Ni and ti.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
144.414 5172.4 !Reducing parameters
5 0 0 0 0 0 !Number of terms in equation
-3.7061 1.0
-81.517 1.50
137.43 1.61
-58.617 1.77
-1.3528 7.3
#DL !---Saturated liquid density---
DL1 !Saturated liquid density equation for fluorine of Lemmon (2010).
?
?```````````````````````````````````````````````````````````````````````````````
?Lemmon, C.K. and Lemmon, E.W., 2010.
?
?Functional Form: D=Dc*[1+SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
? the reducing parameters below, which are followed by rows containing Ni and ti.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
144.414 15.603 !Reducing parameters
5 0 0 0 0 0 !Number of terms in equation
0.21286 0.228
4.4011 0.58
-5.3959 0.908
4.1347 1.24
-0.97544 1.6
#DV !---Saturated vapor density---
DV3 !Saturated vapor density equation for fluorine of Lemmon (2010).
?
?```````````````````````````````````````````````````````````````````````````````
?Lemmon, C.K. and Lemmon, E.W., 2010.
?
?Functional Form: D=Dc*EXP[SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
? the reducing parameters below, which are followed by rows containing Ni and ti.
?
!```````````````````````````````````````````````````````````````````````````````
0. !
10000. !
0. !
0. !
144.414 15.603 !Reducing parameters
6 0 0 0 0 0 !Number of terms in equation
-3.6218 0.454
-55.363 2.3
122.14 2.9
-230.92 4.0
-338.61 6.0
432.18 5.3
@END
c 1 2 3 4 5 6 7 8
c2345678901234567890123456789012345678901234567890123456789012345678901234567890
0.3357 !Lennard-Jones coefficient sigma [nm] for ECS method
112.6 !Lennard-Jones coefficient epsilon/kappa [K] for ECS method