462 lines
24 KiB
Plaintext
462 lines
24 KiB
Plaintext
R13 !Short name
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75-72-9 !CAS number
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Chlorotrifluoromethane !Full name
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CClF3 !Chemical formula {CClF3}
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CFC-13 !Synonym
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104.459 !Molar mass [g/mol]
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92.0 !Triple point temperature [K]
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191.67 !Normal boiling point [K]
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302.0 !Critical temperature [K]
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3879.0 !Critical pressure [kPa]
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5.58 !Critical density [mol/L]
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0.1723 !Acentric factor
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0.51 !Dipole moment [Debye]; value from REFPROP v5.0
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IIR !Default reference state
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10.0 !Version number
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1022 !UN Number :UN:
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halocb !Family :Family:
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???? !Heating value (upper) [kJ/mol] :Heat:
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14400. !GWP (IPCC 2007) :GWP:
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1.0 !ODP (Montreal Protocol 2012) :ODP:
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A1 !Safety Group (ASHRAE Standard 34, 2010) :Safety:
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1S/CClF3/c2-1(3,4)5 !Standard InChI String :InChi:
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AFYPFACVUDMOHA-UHFFFAOYSA-N !Standard InChI Key :InChiKey:
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???? !Alternative fluid for mixing rules :AltID:
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126c90a0 !Hash number from InChI Key :Hash:
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!The fluid files contain general information about the fluid in the first 15 to 20 lines, followed by sections for the
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! equations of state, transport equations, and auxiliary equations. Equations of state are listed first. The NIST recommended
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! equations begin with a hash mark (#). The secondary equations begin with the @ symbol. These symbols can be swapped to
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! select a secondary equation as primary and the primary as secondary. The equation of state section also contains auxiliary
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! equations for the ideal gas heat capacity or ideal gas Helmholtz energy. Below the equations of state (both primary and
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! secondary) are the transport equations, first viscosity and then thermal conductivity. These are then followed by the
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! secondary equations if available. The transport section also contains auxiliary equations required to calculate either the
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! dilute gas state or the critical enhancement. At the end of the file are additional but not necessary auxiliary equations,
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! including simple equations for the vapor pressure, saturated liquid and vapor densities, melting line (for some fluids), and
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! sublimation line (for even fewer fluids). This section also contains the equations for dielectric constant and surface
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! tension if available. The sections are divided by different symbols (these being _-+=^*~) to aid the eye in locating a
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! particular section. Secondary equations are indented 10 spaces to avoid confusion with the NIST recommended equations. The
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! end of the fluid file is marked with @END. Anything below that is ignored.
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! compiled by E.W. Lemmon, NIST Physical and Chemical Properties Division, Boulder, Colorado
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! 06-10-97 EWL, Original version.
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! 11-13-97 EWL, Add Platzer equation, make it the NIST-recommended one.
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! 01-26-01 EWL, Add Magee equation, make it the NIST-recommended one.
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! 05-09-02 MLH, Add viscosity fit, revised k fit, added LJ parameters.
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! 04-19-04 MLH, Update transport references.
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! 09-18-09 KK, Change number of cp0 coefficients from 3 to 4 to match Magee publication.
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! 08-17-10 IDC, Add ancillary equations.
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! 12-06-12 EWL, Add surface tension coefficients of Mulero et al. (2012).
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! 01-05-16 MLH, Change TK6 model to TK3.
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________________________________________________________________________________
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#EOS !---Equation of state---
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BWR !MBWR equation of state for R-13 of Magee et al. (2000).
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:TRUECRITICALPOINT: 302.0 5.58 !True EOS critical point [K, mol/L] (where dP/dD=0 and d^2P/dD^2=0 at constant T)
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:DOI: 10.1023/A:1026446004383
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Magee, J.W., Outcalt, S.L., and Ely, J.F.,
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? "Molar Heat Capacity C(v), Vapor Pressure, and (p, rho, T) Measurements from
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? 92 to 350 K at Pressures to 35 MPa and a New Equation of State for
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? Chlorotrifluoromethane (R13),"
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? Int. J. Thermophys., 21(5):1097-1121, 2000.
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?
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?The uncertainties of the equation of state are 0.15% in density and 2% in heat
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? capacity, except in the critical region. The uncertainty in vapor pressure is
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? 0.1%.
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?
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!```````````````````````````````````````````````````````````````````````````````
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92.0 !Lower temperature limit [K]
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403.0 !Upper temperature limit [K]
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35000.0 !Upper pressure limit [kPa]
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17.85 !Maximum density [mol/L]
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CPP !Pointer to Cp0 model
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104.459 !Molar mass [g/mol]
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92.0 !Triple point temperature [K]
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0.0003288 !Pressure at triple point [kPa]
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17.84 !Density at triple point [mol/L]
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191.67 !Normal boiling point temperature [K]
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0.1723 !Acentric factor
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302.0 3879.0 5.58 !Tc [K], pc [kPa], rhoc [mol/L]
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302.0 5.58 !Reducing parameters [K, mol/L]
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5.58 !gamma
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0.08314471 !Gas constant [L-bar/mol-K]
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32 1 !Nterm, Ncoeff per term
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0.00427710490378 1.06603397093 -38.3065097813
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6615.80211522 -800160.78037 -0.00406405755462
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5.61380767634 -2476.94806929 -63983.4580892
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0.000198818486764 -0.206916891385 74.9317872337
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-0.00431471653965 1.81741326553 -20.6066849491
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-0.136681208829 0.0026049624094 0.287244312242
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-0.0105459756169 582404.815872 -45572194.7029
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11417.4177352 265590.236008 135.24987355
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1282.89104267 0.800900540368 -7033.07137789
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0.00235567665577 1.31830636112 -0.115187941781e-4
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0.00564530387616 0.336242130107
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#AUX !---Auxiliary function for Cp0
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CPP !Ideal gas heat capacity function for R-13 of Magee (2000).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Magee, J.W., Outcalt, S.L., and Ely, J.F., 2000.
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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302.0 8.314471 !Reducing parameters for T, Cp0
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4 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
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1.86012334 0.0
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8.0731452 1.0
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-1.87713639 2.0
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0.0317242858 3.0
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#AUX !---Auxiliary function for PX0
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PX0 !Helmholtz energy ideal-gas function for R-13 of Magee (2000).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Magee, J.W., Outcalt, S.L., and Ely, J.F., 2000.
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?
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!```````````````````````````````````````````````````````````````````````````````
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1 5 0 0 0 0 0 0 !Nterms: ai*log(tau**ti); ai*tau**ti; ai*log(1-exp(bi*tau))
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0.86012334 1.0 !ai, ti for [ai*log(tau**ti)] terms
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-8.3537524800478558 0.0 !aj, ti for [ai*tau**ti] terms
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8.5261368653750207 1.0 !aj, ti for [ai*tau**ti] terms
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0.0267322688741722 -1.0
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-0.205817331477e-04 -2.0
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0.115178395655e-08 -3.0
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--------------------------------------------------------------------------------
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@EOS !---Equation of state---
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FE1 !Bender equation of state for R-13 of Platzer et al. (1990).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Platzer, B., Polt, A., and Maurer, G.,
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? "Thermophysical properties of refrigerants,"
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? Berlin, Springer-Verlag, 1990.
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?
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!```````````````````````````````````````````````````````````````````````````````
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98.15 !Lower temperature limit [K]
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450.0 !Upper temperature limit [K]
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50000.0 !Upper pressure limit [kPa]
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17.699806 !Maximum density [mol/L]
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CP1 !Pointer to Cp0 model
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104.459 !Molar mass [g/mol]
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98.15 !Triple point temperature [K]
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0.0009047 !Pressure at triple point [kPa]
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17.6998 !Density at triple point [mol/L]
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191.738 !Normal boiling point temperature [K]
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0.17469 !Acentric factor
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301.88 3877.0 5.57098 !Tc [K], pc [kPa], rhoc [mol/L]
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301.88 5.57098 !Reducing parameters [K, mol/L]
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8.31451 !Gas constant [J/mol-K]
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22 5 0 0 0 0 0 0 0 0 0 0 !# terms and # coefs/term for normal terms, Gaussian terms, and Gao terms
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-0.62834655992 3. 0. 0. 0. !a(i),t(i),d(i),l(i)
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0.792797111341 4. 0. 0. 0.
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-0.134038992692 5. 0. 0. 0.
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0.761143010172 0. 1. 0. 0.
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-1.94465098795 1. 1. 0. 0.
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0.940938700406 2. 1. 0. 0.
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-1.08107050239 3. 1. 0. 0.
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0.117501564976 4. 1. 0. 0.
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0.228305167217 0. 2. 0. 0.
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-0.403338888789 1. 2. 0. 0.
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0.37558571342 2. 2. 0. 0.
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-0.0617543677315 0. 3. 0. 0.
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0.170326226881 1. 3. 0. 0.
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0.0536612457231 0. 4. 0. 0.
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-0.151603010301 1. 4. 0. 0.
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0.0252033265074 1. 5. 0. 0.
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0.62834655992 3. 0. 2. 0.98230055
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-0.792797111341 4. 0. 2. 0.98230055
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0.134038992692 5. 0. 2. 0.98230055
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-0.0399863840975 3. 2. 2. 0.98230055
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0.436410910529 4. 2. 2. 0.98230055
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-0.448724904991 5. 2. 2. 0.98230055
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@AUX !---Auxiliary function for Cp0
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CP1 !Ideal gas heat capacity function for R-13.
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Platzer, B., Polt, A., and Maurer, G.,
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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1.0 8.31451 !Reducing parameters for T, Cp0
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5 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
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2.4766458 0.0
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0.018074269 1.0
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0.000021945535 2.0
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-0.85810657e-7 3.0
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0.63199171e-10 4.0
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++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
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#TRN !---ECS Transport---
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ECS !Extended Corresponding States model (Propane reference); fitted to data for R-13.
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:DOI: 10.1021/ie0300880
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Unpublished; uses method described in the following reference:
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?Huber, M.L., Laesecke, A., and Perkins, R.A.,
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? "Model for the Viscosity and Thermal Conductivity of Refrigerants, Including
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? a New Correlation for the Viscosity of R134a,"
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? Ind. Eng. Chem. Res., 42(13):3163-3178, 2003. doi: 10.1021/ie0300880
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?
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?THERMAL CONDUCTIVITY
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? The ECS parameters for thermal conductivity were based in part on the data of:
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? Makita, T., Tanaka, Y., Morimoto, Y., Noguchi, M., and Kubota, H., "Thermal Conductivity of Gaseous Fluorocarbon Refrigerants R12, R13, R22, and R23 under Pressure," Int. J. Thermophys., 2:249-268, 1981.
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? Yata, J., Minamiyama, T., and Tanaka, S., "Measurement of Thermal Conductivity of Liquid Fluorocarbons," Int. J. Thermophys., 5:209-218, 1984.
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? Tsvetkov, O.B., Laptev, Yu.A., and Vasilkov, A.I., "The Results of Measurements of Thermal Conductivity of Gaseous Freons with the Heating Wire Method," Mashinyi i Apparatyi Cholodilnoj, Kriogennoh Techniki i Kondizionirovaniyi Vosducha, Collect No. 2, 54-6, Leningradskij Tech. Inst., 1977.
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? Geller, V.Z., "Investigation of the Thermal Conductivity of Methane Row Freons," Teplofiz. Svoistva Veshchestv Mater., No. 8, Rabinovich, V. A., Ed., Standards Publ.: Moscow, 162-76, 1975.
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? Sadyikov, A.Kh., "Experimental Investigation of Some Thermophysical Properties of Polyoxy Compounds," Ph.D. Thesis, Kazan, Tech. Inst. for Refrigeration, Kazan, USSR, 1978.
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? Potapov, M. D., "The Thermal Conductivity of Liquid Binary Mixtures of Halogenated Hydrocarbons," Ph. D. Thesis, OTIPP, Odessa, 1988.
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? Sadyikov, A.K., Brykov, V.P., and Mukhamedzyanov, G.K., "Thermal Conductivity of Low-Temperature Freons," Teplo- Massoobmen Khim. Tekhnol. Collect. Vol., No. 3:31-5, 1975.
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? Geller, V.Z., "Thermal Conductivity of Some Liquid Refrigerants at Low Temperature," Teplofiz. Svoistva Veshchestv Mter., Collect. Vol., No. 9, Standards Publ.: Moscow, 147-61, 1976.
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? Average absolute deviations of the fit from the experimental data are:
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? Makita: 8.48%; Yata: 1.69%; Tsvetkov: 1.82%; Geller: 4.94%; Sadyikov, 1978:1.76;
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? Potapov:1.17%; Sadyikov, 1975: 7.14%; Geller, 1976: 1.66%. Overall: 5.90%.
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?
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?VISCOSITY
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? The ECS parameters for viscosity were based in part on the data of:
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? Diller, D.E. and Van Poolen, L. J., "Measurement of Viscosities of Saturated and Compressed Fluid Chlorotrifluoromethane (R13)," Cryogenics 29:1063-6, 1989. doi: 10.1016/0011-2275(89)90261-0
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? Geller, V.Z., Ivanchenko, S.I., and Kronberg, A.V., "Study of Dynamic Viscosity Coefficient of Methane Type Freons," Teplofiz. Svoistva Veshchestv. Mater., Collect. V. A. Rabinovich, Ed., Standards Publ.: Moscow, pp. 148-161, 1975.
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? Geller, V.Z., "Viscosity of Freons of the Methane, Ethane, and Propane Series. Generalizations of Experimental Data," Teplofiz. Svoistva Veshchestv. Mater., No. 15, Sychev, V.V., Ed., Standards Publ.: Moscow, pp. 89-114, 1980.
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? Kronberg, A.V., "Experimental and Theoretical Investigation of the Viscosity of Methane and Ethane Row's Refrigerants," Ph.D. Dissertation, Azer. Inst. Neft. Khim., Baku, USSR, 1979.
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? Takahashi, M., Takahashi, S., and Iwasaki, H., "Viscosity of Gaseous Chlorotrifluoromethane (R13) Under Pressure," J. Chem. Eng. Data, 30:10-14, 1985. doi: 10.1021/je00039a004
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? Average absolute deviations of the fit from the experimental data are:
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? Diller: 4.54%; Geller, 1975: 5.71%; Geller, 1980: 3.36%;
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? Kronberg: 1.87%; Takahashi: 0.64%.
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? Overall: 2.96%.
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?
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?The Lennard-Jones parameters were taken from Takahashi, M., Takahashi, S., and Iwasaki, H., "Viscosity of Gaseous Chlorotrifluoromethane (R13) Under Pressure," J. Chem. Eng. Data, 30:14-17, 1985.
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?
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!```````````````````````````````````````````````````````````````````````````````
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92.0 !Lower temperature limit [K]
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403.0 !Upper temperature limit [K]
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35000.0 !Upper pressure limit [kPa]
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17.85 !Maximum density [mol/L]
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FEQ PROPANE.FLD
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VS1 !Model for reference fluid viscosity
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TC1 !Model for reference fluid thermal conductivity
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NUL !Large molecule identifier
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1 !Lennard-Jones flag (0 or 1) (0 => use estimates)
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0.4971 !Lennard-Jones coefficient sigma [nm] for ECS method
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204.0 !Lennard-Jones coefficient epsilon/kappa [K] for ECS method
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2 0 0 !Number of terms in f_int term in Eucken correlation, spare1, spare2
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0.00107447 0. 0. 0. !Coefficient, power of T, spare1, spare2
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6.42373e-7 1. 0. 0. !Coefficient, power of T, spare1, spare2
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2 0 0 !Number of terms in psi (visc shape factor): poly,spare1,spare2
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0.976177 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
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0.0148047 0. 1. 0. !Coefficient, power of Tr, power of Dr, spare
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2 0 0 !Number of terms in chi (t.c. shape factor): poly,spare1,spare2
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1.1394 0. 0. 0. !Coefficient, power of Tr, power of Dr, spare
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-0.0365562 0. 1. 0. !Coefficient, power of Tr, power of Dr, spare
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TK3 !Pointer to critical enhancement auxiliary function
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#AUX !---Auxiliary function for the thermal conductivity critical enhancement
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TK3 !Simplified thermal conductivity critical enhancement for R-13 of Olchowy and Sengers (1989).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Olchowy, G.A. and Sengers, J.V.,
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? "A Simplified Representation for the Thermal Conductivity of Fluids in the Critical Region,"
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? Int. J. Thermophys., 10:417-426, 1989. doi: 10.1007/BF01133538
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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9 0 0 0 !# terms: CO2-terms, spare, spare, spare
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1.0 1.0 1.0 !Reducing parameters for T, rho, tcx [mW/(m-K)]
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0.63 !Nu (universal exponent)
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1.239 !Gamma (universal exponent)
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1.03 !R0 (universal amplitude)
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0.063 !Z (universal exponent--not used for t.c., only viscosity)
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1.0 !C (constant in viscosity eqn = 1/[2 - (alpha + gamma)/(2*nu)], but often set to 1)
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0.194e-9 !Xi0 (amplitude) [m]
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0.0496 !Gam0 (amplitude) [-]
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3.49636e-10 !Qd_inverse (modified effective cutoff parameter) [m]; fitted to data
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453.0 !Tref (reference temperature)=1.5*Tc [K]
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~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
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#STN !---Surface tension---
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ST1 !Surface tension model for R-13 of Mulero et al. (2012).
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:DOI: 10.1063/1.4768782
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Mulero, A., Cachadi<64>a, I., and Parra, M.I.,
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? "Recommended Correlations for the Surface Tension of Common Fluids,"
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? J. Phys. Chem. Ref. Data, 41(4), 043105, 2012. doi: 10.1063/1.4768782
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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1 !Number of terms in surface tension model
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302 !Critical temperature used in fit (dummy)
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0.05045 1.269 !Sigma0 and n
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#PS !---Vapor pressure---
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PS5 !Vapor pressure equation for R-13 of Cullimore (2010).
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?
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?```````````````````````````````````````````````````````````````````````````````
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?Cullimore, I.D., 2010.
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?
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?Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc
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? are the reducing parameters below, which are followed by rows containing Ni and ti.
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?
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!```````````````````````````````````````````````````````````````````````````````
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0. !
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10000. !
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0. !
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0. !
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302.0 3879.0 !Reducing parameters
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5 0 0 0 0 0 !Number of terms in equation
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-6.9311 1.0
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1.8281 1.5
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-2.1901 2.5
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-3.8177 6.0
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2.0803 8.0
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#DL !---Saturated liquid density---
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DL1 !Saturated liquid density equation for R-13 of Cullimore (2010).
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?
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?```````````````````````````````````````````````````````````````````````````````
|
||
?Cullimore, I.D., 2010.
|
||
?
|
||
?Functional Form: D=Dc*[1+SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
|
||
? the reducing parameters below, which are followed by rows containing Ni and ti.
|
||
?
|
||
!```````````````````````````````````````````````````````````````````````````````
|
||
0. !
|
||
10000. !
|
||
0. !
|
||
0. !
|
||
302.0 5.58 !Reducing parameters
|
||
5 0 0 0 0 0 !Number of terms in equation
|
||
9.5469 0.51
|
||
-24.017 0.72
|
||
33.365 0.94
|
||
-26.837 1.2
|
||
10.638 1.4
|
||
|
||
|
||
#DV !---Saturated vapor density---
|
||
DV3 !Saturated vapor density equation for R-13 of Cullimore (2010).
|
||
?
|
||
?```````````````````````````````````````````````````````````````````````````````
|
||
?Cullimore, I.D., 2010.
|
||
?
|
||
?Functional Form: D=Dc*EXP[SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are
|
||
? the reducing parameters below, which are followed by rows containing Ni and ti.
|
||
?
|
||
!```````````````````````````````````````````````````````````````````````````````
|
||
0. !
|
||
10000. !
|
||
0. !
|
||
0. !
|
||
302.0 5.58 !Reducing parameters
|
||
5 0 0 0 0 0 !Number of terms in equation
|
||
-3.1949 0.414
|
||
-7.3425 1.41
|
||
-21.966 3.7
|
||
-51.459 7.7
|
||
-85.359 15.0
|
||
|
||
|
||
@END
|
||
c 1 2 3 4 5 6 7 8
|
||
c2345678901234567890123456789012345678901234567890123456789012345678901234567890
|
||
|
||
|
||
@EOS !Equation of state specification
|
||
ECS Thermodynamic Extended Corresponding States model w/ T- and rho-dependent shape factors.
|
||
?
|
||
?```````````````````````````````````````````````````````````````````````````````
|
||
?Huber, M.L. and Ely, J.F.,
|
||
? "A predictive extended corresponding states model for pure and mixed
|
||
? refrigerants including an equation of state for R134a,"
|
||
? Int. J. Refrigeration, 17(1):18-31, 1994. doi: 10.1016/0140-7007(94)90083-3
|
||
?
|
||
?ECS parameters fitted by E.W. Lemmon, NIST, 06-11-97
|
||
? Average absolute deviations of the fit from the experimental data are:
|
||
? PVT: 0.28%; Pv: 0.15%
|
||
?
|
||
?DATA SOURCES
|
||
? Michels, A., Wassenaar, T., Wolkers, G.J., Prins, C., and Klundert, L.V.D., P-V-T data and thermodynamical properties of Freon-12 (CC1 (2)F(2)) and Freon-13 (CC1F(3)) fluorocarbons at temperatures between 0 and 150 C and at pressures up to 400 atm. J. Chem. Eng. Data, 11(4):449-452 (1966). doi: 10.1021/je60031a001
|
||
?
|
||
!```````````````````````````````````````````````````````````````````````````````
|
||
173.0 !Lower temperature limit [K]
|
||
500.0 !Upper temperature limit [K]
|
||
60000.0 !Upper pressure limit [kPa]
|
||
15.2889 !Maximum density [mol/L]
|
||
CP2 !Pointer to Cp0 model
|
||
PROPANE.FLD
|
||
BWR !Pointer to reference fluid model
|
||
0.15238 !Acentric factor for R12 used in shape factor correlation
|
||
0.27627 !Critical compressibility for R12 used in correlation
|
||
0.17469 !Acentric factor for fluid used in shape factor correlation
|
||
302.35 !Critical temperature [K]
|
||
3915.0 !Critical pressure [kPa]
|
||
5.50934 !Critical density [mol/L]
|
||
3 !Number of temperature coefficients for 'f' shape factor
|
||
-0.349641790 0. ! alpha1 of Huber & Ely
|
||
-0.907689146 1. ! alpha2 (log(Tr) term)
|
||
-0.000653134886 1.
|
||
1 !Number of density coefficients for 'f' shape factor
|
||
0.00210751423 1. ! rho coefficient and power in temperature
|
||
2 !Number of temperature coefficients for 'h' shape factor
|
||
0.924297063 0. ! beta1 of Huber & Ely
|
||
0.515294928 1. ! beta2 (log(Tr) term)
|
||
0 !Number of density coefficients for 'h' shape factor
|
||
|
||
|
||
@AUX !---Auxiliary model specification for Cp0
|
||
CP2 ideal gas heat capacity function
|
||
?
|
||
?```````````````````````````````````````````````````````````````````````````````
|
||
?Huber, M.L. and Ely, J.F.,
|
||
?
|
||
!```````````````````````````````````````````````````````````````````````````````
|
||
0. !
|
||
10000. !
|
||
0. !
|
||
0. !
|
||
1.0 1.0 !Reducing parameters for T, Cp0
|
||
3 0 0 0 0 0 0 !Nterms: polynomial, exponential, cosh, sinh
|
||
15.32010608 0.0
|
||
0.22223115 1.0
|
||
-0.00016422906 2.0
|